Fragrance Oil: Florencia

Safety Data Sheet + IFRA as of 9/9/2021

Section 2. Hazards identification 2.1 Classification of the substance or mixture

Class and category of danger:

Skin Corrosion / Irritation Category 2

Eye Damage / Irritation Category 2

Sensitization - Skin Category 1

Hazardous to the Aquatic Environment - Acute Hazard Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 1 H315, Causes skin irritation.

H317, May cause an allergic skin reaction.

H319, Causes serious eye irritation.

H410, Very toxic to aquatic life with long lasting effects.

2.2 Label elements

Signal word: Warning

Hazard statements: H315, Causes skin irritation.

H317, May cause an allergic skin reaction.

H319, Causes serious eye irritation.

H410, Very toxic to aquatic life with long lasting effects.

Precautionary statements:

P261, Avoid breathing vapour or dust.

P264, Wash hands and other contacted skin thoroughly after handling.

P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment.

P280, Wear protective gloves/eye protection/face protection.

P302/352, IF ON SKIN: Wash with plenty of soap and water.

P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P333/313, If skin irritation or rash occurs: Get medical advice/attention.

P337/313, If eye irritation persists: Get medical advice/attention.

P362, Take off contaminated clothing and wash before reuse.

P391, Collect spillage.

P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Section 3. Composition / information on ingredients

3.2 Mixtures Contains:


Name

CAS

EC

%

GHS Classification

ISO E SUPER

54464-57-2

10-<20%

Skin Irrit. 2-Skin Sens. 1B-Aquatic Acute 2-Aquatic Chronic 1;H315-H317-H401-

H410

HEDIONE

24851-98-7

10-<20%

Aquatic Acute 3;H402

Benzyl benzoate

120-51-4

204-402-9

5-<10%

Acute Tox. 4-Acute Tox. 5-Aquatic Acute 1-Aquatic Chronic 2;H302-H313-H400-

H411

GALAXOLIDE NEAT

1222-05-05

5-<10%

Skin Irrit. 3-Aquatic Acute 1-Aquatic Chronic 1;H316-H410

HEXYL SALICYLATE

6259-76-3

5-<10%

Skin Irrit. 3-Skin Sens. 1B-Aquatic Acute 1-Aquatic Chronic 1;H316-H317-H410

LILIAL SUB

1-<5%

Skin Irrit. 3-Eye Irrit. 2-Skin Sens. 1; H316-H317-H319

FLOROL/FLOROSA

63500-71-0

1-<5%

Eye Irrit. 2A;H319

ETHYLENE BRASSYLATE

105-95-3

1-<5%

Aquatic Acute 2;H401

Benzyl salicylate

118-58-1

204-262-9

1-<5%

Acute Tox. 5-Eye Irrit. 2B-Skin Sens. 1B-Aquatic Acute 2-Aquatic Chronic 3;H303-

H317-H320-H401-H412

ETHYL LINALOOL

10339-55-6

1-<5%

Flam. Liq. 4-Acute Tox. 5-Skin Irrit. 3-Eye Irrit. 2A-Skin Sens. 1B-Aquatic Acute 3;

H227-H303-H316-H317-H319-H402

CIS-3 HEXENYL SALICYLATE

65405-77-8

1-<5%

Acute Tox. 5-Aquatic Acute 1-Aquatic Chronic 2;H303-H400-H411

di-Citronellol

106-22-9

203-375-0

1-<5%

Acute Tox. 5-Acute Tox. 5-Skin Irrit. 2- Eye Irrit. 2A-Skin Sens. 1B-Aquatic Acute

2;H303-H313-H315-H317-H319-H401

CANTHOXAL

5462-06-06

1-<5%

Acute Tox. 5-Skin Sens. 1B-Aquatic Acute 2;H303-H317-H401

ETHYL LINALYL ACETATE

61931-80-4

1-<5%

Skin Irrit. 2-Eye Irrit. 2A-Skin Sens. 1B-Aquatic Acute 2-Aquatic Chronic 2;H315-

H317-H319-H411

Linalool

78-70-6

201-134-4

1-<5%

Flam. Liq. 4-Acute Tox. 5-Skin Irrit. 2-Eye Irrit. 2A-Skin Sens. 1B-Aquatic Acute 3;

H227-H303-H315-H317-H319-H402

Geraniol

106-24-1

203-377-1

1-<5%

Acute Tox. 5-Skin Irrit. 2-Eye Dam. 1-Skin Sens. 1-Aquatic Acute 3;H303-

H315-H317-H318-H402

LINALYL ACETATE

115-95-7

0.1-<1%

Flam. Liq. 4-Skin Irrit. 2-Eye Irrit. 2B-Skin Sens. 1B-Aquatic Acute 3;H227-H315-

H317-H320-H402

CASHMERAN ( R )

33704-61-9

0.1-<1%

Acute Tox. 5-Skin Irrit. 2-Eye Irrit. 2A-Skin Sens. 1B-Aquatic Acute 2-Aquatic

Chronic 2;H303-H315-H317-H319-H411

BACDANOL

28219-61-6

0.1-<1%

Skin Irrit. 2-Eye Irrit. 2A-Aquatic Acute 2- Aquatic Chronic 2;H315-H319-H411

CITRONELLYL FORMATE

105-85-1

0.1-<1%

Skin Irrit. 2-Skin Sens. 1B-Aquatic Acute 2;H315-H317-H401

Hydroxycitronellal

107-75-5

203-518-7

0.1-<1%

Eye Irrit. 2A-Skin Sens. 1B-Aquatic Acute 3;H317-H319-H402

Coumarin

91-64-5

202-086-7

0.1-<1%

Acute Tox. 4-Skin Sens. 1B-Aquatic Acute 3;H302-H317-H402

ISO MENTHONE

0491-07-06

0.1-<1%

Flam. Liq. 4-Acute Tox. 5-Skin Irrit. 2-Skin Sens. 1B-Aquatic Acute 3;H227-

H303-H315-H317-H402

MENTHONE

10458-14-7

0.1-<1%

Flam. Liq. 4-Acute Tox. 4-Skin Irrit. 2-Skin Sens. 1B-Aquatic Acute 3-Aquatic

Chronic 3;H227-H302-H315-H317-H412

MUGUET ALCOHOL

13351-61-6

0.1-<1%

Acute Tox. 4-Skin Irrit. 2-Eye Irrit. 2A-Aquatic Acute 3-Aquatic Chronic 3;H302-

H315-H319-H412

CARYOPHYLLENE BETA

87-44-5

0.1-<1%

Skin Sens. 1B-Asp. Tox 1-Aquatic Chronic 4;H304-H317-H413

MOUSSE METRA ( C )

4707-47-5

0.1-<1%

Skin Sens. 1B-Aquatic Acute 2;H317- H401

BOURGEONAL

18127-01-0

0.1-<1%

Flam. Liq. 4-Acute Tox. 5-Skin Irrit. 2-

ROSE OXIDE RACEMIC

|16409-43-1

0.1-<1%

Flam. Liq. 4-Acute Tox. 5-Skin Irrit. 2-Eye Irrit. 2A-Repr. 2-Aquatic Acute 3;H227-

H303-H315-H319-H361-H402

AMBRETTOLIDE

128645-51-40

0.1-<1%

Aquatic Acute 1-Aquatic Chronic 1;H410

CEDARWOOD OIL VIRGINIA

8000-21 tel:2

0.1-<1%

Skin Irrit. 3-Asp. Tox 1-Aquatic Acute 1- Aquatic Chronic 1;H304-H316-H410

DAMASCENONE

23696-85-7

0.1-<1%

Acute Tox. 5-Skin Irrit. 2-Skin Sens. 1A-Aquatic Acute 2-Aquatic Chronic 2;H313-

H315-H317-H411

TRIPLAL

|27939-60-2

0.1-<1%

Flam. Liq. 4-Acute Tox. 5-Skin Irrit. 2-Eye Irrit. 2A-Skin Sens. 1B-Aquatic Acute 2- Aquatic Chronic 2;H227-H303-H315- H317-H319-H411

Substances with Community workplace exposure limits, not listed above:

Not Applicable

Section 4. First-aid measures

4.1 Description of first aid measures

IF ON SKIN: Wash with plenty of soap and water.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

4.2 Most important symptoms and effects, both acute and delayed

Causes skin irritation.

May cause an allergic skin reaction. Causes serious eye irritation.

4.3 Indication of any immediate medical attention and special treatment needed

None expected, see Section 4.1 for further information.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable media: Carbon dioxide, Dry chemical, Foam.

5.2 Special hazards arising from the substance or mixture

In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds.

5.3 Advice for fire fighters:

In case of insufficient ventilation, wear suitable respiratory equipment.

Section 6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:

Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8.

6.2 Environmental precautions:

Keep away from drains, surface and ground water, and soil.

6.3 Methods and material for containment and cleaning up:

Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations.

6.4 Reference to other sections:

Also refer to sections 8 and 13.

Section 7. Handling and storage

7.1 Precautions for safe handling:

Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product.

7.2 Conditions for safe storage, including any incompatibilities:

Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge.

7.3 Specific end use(s):

Fragrances: Use in accordance with good manufacturing and industrial hygiene practices.

Section 8. Exposure controls/personal protection

8.1 Control parameters

Workplace exposure limits: Not Applicable

8.2 Exposure Controls

Eye / Skin Protection

Wear protective gloves/eye protection/face protection

Respiratory Protection

Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material.

Section 9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance:Clear free-flowing liquid without sediment

Odour:Conforms To Standard

pH:Not determined

Initial boiling point / range: Not determined

Flash point: > 93 °C

Vapour pressure:Not determined

Relative density: 0.9830 - 0.9930

Solubility(ies):Not determined

9.2 Other information:Not determined

Section 10. Stability and reactivity

10.1 Reactivity:

Presents no significant reactivity hazard, by itself or in contact with water.

10.2 Chemical stability:

Good stability under normal storage conditions.

10.3 Possibility of hazardous reactions:

Not expected under normal conditions of use.

10.4 Conditions to avoid:

Avoid extreme heat.

10.5 Incompatible materials:

Avoid contact with strong acids, alkalis or oxidising agents.

10.6 Hazardous decomposition products:

Not expected.

Section 11. Toxicological information 11.1 Information on toxicological effects

This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in UN GHS.

Causes skin irritation.

May cause an allergic skin reaction.

Causes serious eye irritation.

Assumed Toxicity Value (LD50 or ATE) for Acute Oral Toxicity: >5000

Assumed Toxicity Value (LD50 or ATE) for Acute Dermal Toxicity:>5000

Assumed Toxicity Value (LC50 or ATE) for Acute Inhalation Toxicity: Not Available

Inhalation Route:Not Available

Information about hazardous ingredients in the mixture


Ingredient

CAS

EC

LD50/ATE Oral

LD50/ATE Dermal

LC50/ATE Inhalation

LC50 Route

Benzyl benzoate

120-51-4

204-402-9

1500

4000

Not available

Not available

Refer to Sections 2 and 3 for additional information.

Section 12. Ecological information

12.1 Toxicity:

Very toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability: Not available

12.3 Bioaccumulative potential: Not available

12.4 Mobility in soil: Not available

12.5 Results of PBT and vPvB assessment: Not available

This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.

12.6 Other adverse effects: Not available

Section 13. Disposal considerations

13.1 Waste treatment methods:

Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal.

Section 14. Transport information

14.1 UN number: UN3082

14.2 UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ISO E SUPER, GALAXOLIDE NEAT)

14.3 Transport hazard class(es): 9

Sub Risk:

14.4. Packing Group: III

14.5 Environmental hazards:This is an environmentally hazardous substance.

14.6 Special precautions for user: none additional 

14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code:

Not applicable

Section 15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Additional formulation properties: 2 entries

15.2 Chemical Safety Assessment

A Chemical Safety Assessment has not been carried out for this product.

Section 16. Other information

Concentration % Limits:EH A1=86.49% EH A2=7.87% EH A3=0.78186083% EH C1=74.98% EH C2=7.21% EH C3=0.72006682% EH C4=50.30% SCI 2=45.45% SCI 3=3. 68% EDI 2A=34.65% SS 1=6.13%

Total Fractional Values: EH A1=1.16 EH A2=12.71 EH A3=127.90 EH C1=1.33 EH C2=13.88 EH C3=138.88 EH C4=1.99 SCI 2=2.20 SCI 3=27.17 EDI 2A=2.89 SS 1=16. 30

Key to revisions:

Not applicable

Key to abbreviations:


Abbreviation

Meaning

Acute Tox. 4

Acute Toxicity Oral Category

Acute Tox. 5

Acute Toxicity Dermal Category 5

Acute Tox. 5

Acute Toxicity Oral Category 5

Aquatic Acute T

Hazardous to the Aquatic Environment Acute Hazard Category 1

Aquatic Acute 2

Hazardous to the Aquatic Environment Acute Hazard Category 2

Aquatic Acute 3

Hazardous to the Aquatic Environment Acute Hazard Category 3

Aquatic Chronic T

Hazardous to the Aquatic Environment Long-term Hazard Category 1

Aquatic Chronic 2

Hazardous to the Aquatic Environment Long-term Hazard Category 2

Aquatic Chronic 3

Hazardous to the Aquatic Environment Long-term Hazard Category 3

Aquatic Chronic 4

Hazardous to the Aquatic Environment Long-term Hazard Category 4

Asp. Tox 1

Aspiration Hazard Category 1

Eye Dam. t

Eye Damage / Irritation Category

Eye Irrit. 2

Eye Damage / Irritation Category 2

Eye Irrit. 2A

Eye Damage / Irritation Category 2A

Eye Irrit. 2B

Eye Damage / Irritation Category 2B

Flam. Liq. 4

Flammable Liquid, Hazard Category 4

H227

Combustible liquid.

H302

Harmful if swallowed.

H303

May be harmful if swallowed.

H304

May be fatal if swallowed and enters airways.

H313

May be in harmful in contact with skin.

H315

Causes skin irritation.

H316

Causes mild skin irritation.

H317

May cause an allergic skin reaction.

H318

Causes serious eye damage.

H319

Causes serious eye irritation.

H320

Causes eye irritation.

H361

Suspected of damaging fertility or the unborn child (exposure route).

H373

May cause damage to organs (organs) through prolonged or repeated exposure (exposure route).

H400

/Very toxic to aquatic life.

H401

Toxic to aquatic life.

H402

Harmful to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

H411

Toxic to aquatic life with long lasting effects.

H412

Harmful to aquatic life with long lasting effects.

H413

May cause long lasting harmful effects to aquatic life.

P202

Do not handle until all safety precautions have been read and understood.

P210

Keep away from heat, sparks, open flames and hot surfaces. No smoking.

P260

Do not breathe vapour or dust.

P261

Avoid breathing vapour or dust.

P264

Wash hands and other contacted skin thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P272

Contaminated work clothing should not be allowed out of the workplace.

P273

Avoid release to the environment.

P280

Wear protective gloves/eye protection/face protection.

P301/310

IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P301/312

IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell.

P302/352

IF ON SKIN: Wash with plenty of soap and water.

P305/351/338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308/313

IF exposed or concerned: Get medical advice/attention.

P310

Immediately call a POISON CENTER or doctor/physician.

P312

Call a POISON CENTRE or doctor/physician if you feel unwell.

P330

Rinse mouth.

P331

Do not induce vomiting.

P332/313

If skin irritation occurs: Get medical advice/attention.

P333/313

If skin irritation or rash occurs: Get medical advice/attention.

P337/313

If eye irritation persists: Get medical advice/attention.

P362

Take off contaminated clothing and wash before reuse.

P363

Wash contaminated clothing before reuse.

P370/378

In case of fire: Use carbon dioxide, dry chemical, foam for extinction.

P391

Collect spillage.

P403/235

Store in a well-ventilated place. Keep cool.

P405

Store locked up.

P501

Dispose of contents/container to approved disposal site, in accordance with local regulations.

Repr. 2

Toxic to Reproduction Category 2

STOT RE 2

Specific Target Organ Toxicity (Repeated Exposure) Category 2

Skin Irrit. 2

Skin Corrosion / Irritation Category 2

Skin Irrit. 3

Skin Corrosion / Irritation Category 3

Skin Sens. 1

Sensitization Skin Category 1

Skin Sens. 1A

Sensitization Skin Category 1A

Skin Sens. 1B

Sensitization Skin Category 1 B

The information in this safety data sheet is to the best of our knowledge true and accurate but all data, instructions, recommendations and/or suggestions are made without guarantee.

CERTIFICATE OF CONFORMITY WITH IFRA STANDARDS

This Certificate assesses the conformity of the fragrance mixture with IFRA Standards and provides restrictions for use as necessary. It is based only on those materials subject to IFRA Standards for the toxicity endpoints described in each Standard.

This Certificate does therefore not replace a comprehensive safety assessment of the fragrance mixture.

SCOPE OF THE CERTIFICATE:

Florencia

COMPULSORY INFORMATION:

We certify that the above mixture is in compliance with the Standards of the INTERNATIONAL FRAGRANCE ASSOCIATION (IFRA), up to and including the 49th Amendment to the IFRA Code of Practice (published January 2020), provided it is used in the following categories at a maximum concentration level of:

 

IFRA Categories

[see Annex 1 below for details]

Maximum Level of use (%)

IFRA Category 1

Not approved

IFRA Category 2

2.30%

IFRA Category 3

0.61%

IFRA Category 4

43.00%

IFRA Category 5A

6.66%

IFRA Category 5B

0.94%

IFRA Category 5C

1.11%

IFRA Category 5D

0.31%

IFRA Category 6

Not approved

IFRA Category 7A

1.27%

IFRA Category 7B

1.27%

IFRA Category 8

0.31%

IFRA Category 9

3.00%

IFRA Category 10A

3.00%

IFRA Category 10B

6.66%

IFRA Category 11A

0.31%

IFRA Category 11B

0.31%

IFRA Category 12

Not limited