Fragrance Oil: Calle 23

Safety Data Sheet + IFRA as of 9/9/2021

Section 2. Hazards identification 2.1 Classification of the substance or mixture

Class and category of danger:

Skin Corrosion / Irritation Category 2

Eye Damage / Irritation Category 2

Sensitization - Skin Category 1

Hazardous to the Aquatic Environment - Acute Hazard Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 1 H315, Causes skin irritation.

H317, May cause an allergic skin reaction.

H319, Causes serious eye irritation.

H410, Very toxic to aquatic life with long lasting effects.

2.2 Label elements

Signal word: Warning

Hazard statements: H315, Causes skin irritation.

H317, May cause an allergic skin reaction.

H319, Causes serious eye irritation.

H410, Very toxic to aquatic life with long lasting effects.

Precautionary statements:

P261, Avoid breathing vapour or dust.

P264, Wash hands and other contacted skin thoroughly after handling.

P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment.

P280, Wear protective gloves/eye protection/face protection.

P302/352, IF ON SKIN: Wash with plenty of soap and water.

P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P333/313, If skin irritation or rash occurs: Get medical advice/attention.

P337/313, If eye irritation persists: Get medical advice/attention.

P362, Take off contaminated clothing and wash before reuse.

P391, Collect spillage.

P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Section 3. Composition / information on ingredients

3.2 Mixtures Contains:


Name

CAS

EC

%

GHS Classification

E ISO E SUPER

154464-57-2

20-<50%

Skin Irrit. 2-Skin Sens. 1B-Aquatic Acute 2-Aquatic Chronic 1;H315-H317-H401-

H410

Benzyl benzoate

120-51-4

204-402-9

10-<20%

Acute Tox. 4-Acute Tox. 5-Aquatic Acute 1-Aquatic Chronic 2;H302-H313-H400-

H411

GALAXOLIDE NEAT

1222-05-05

5-<10%

Skin Irrit. 3-Aquatic Acute 1-Aquatic Chronic 1;H316-H410

HEDIONE

24851-98-7

5-<10%

Aquatic Acute 3;H402

VANILLIN ( C)

121-33-5

1-<5%

Acute Tox. 5-Eye Irrit. 2A-Aquatic Acute 3;H303-H319-H402

SANDALORE

65113-99-7

1-<5%

Skin Irrit. 3-Eye Irrit. 2A-Aquatic Acute 2- Aquatic Chronic 2;H316-H319-H411

ALDEHYDE C 14

104-67-6

1-<5%

Skin Irrit. 3-Aquatic Acute 3-Aquatic Chronic 3;H316-H412

CASHMERAN (R )

33704-61-9

1-<5%

Acute Tox. 5-Skin Irrit. 2-Eye Irrit. 2A- Skin Sens. 1B-Aquatic Acute 2-Aquatic

Chronic 2;H303-H315-H317-H319-H411

Linalool

78-70-6

201-134-4

1-<5%

Flam. Liq. 4-Acute Tox. 5-Skin Irrit. 2-Eye Irrit. 2A-Skin Sens. 1B-Aquatic Acute 3;

H227-H303-H315-H317-H319-H402

EBANOL

67801-20-1

1-<5%

Aquatic Acute 2-Aquatic Chronic 2;H411

NECTARYL

95962-14-4

1-<5%

Eye Irrit. 2A-Aquatic Acute 1-Aquatic Chronic 3;H319-H400-H412

Coumarin

91-64-5

202-086-7

1-<5%

Acute Tox. 4-Skin Sens. 1B-Aquatic Acute 3;H302-H317-H402

LEMON OIL CALIFORNIA

8008-56-8

1-<5%

Flam. Liq. 3-Skin Irrit. 2-Skin Sens. 1- Repr. 2-Asp. Tox 1-Aquatic Acute 2- Aquatic Chronic 2;H226-H304-H315- H317-H361-H411

AMBRETTOLIDE

28645-51-4

1-<5%

Aquatic Acute 1-Aquatic Chronic 1;H410

BACDANOL

28219-61-6

1-<5%

Skin Irrit. 2-Eye Irrit. 2A-Aquatic Acute 2- Aquatic Chronic 2;H315-H319-H411

ETHYL LINALOOL

10339-55-6

1-<5%

Flam. Liq. 4-Acute Tox. 5-Skin Irrit. 3-Eye Irrit. 2A-Skin Sens. 1B-Aquatic Acute 3;

H227-H303-H316-H317-H319-H402

FLOROL/FLOROSA

63500-71-0

1-<5%

Eye Irrit. 2A;H319

GAMMA DECALACTONE

706-14-9

1-<5%

Skin Irrit. 3;H316

ETHYL MALTOL ( C )

4940-11-8

1-<5%

Acute Tox. 4-Aquatic Acute 2;H302-H401

LINALYL ACETATE

115-95-7

0.1-<1%

Flam. Liq. 4-Skin Irrit. 2-Eye Irrit. 2B-Skin Sens. 1B-Aquatic Acute 3;H227-H315-

H317-H320-H402

VERTOFIX COEUR

32388-55-9

0.1-<1%

Acute Tox. 5-Skin Sens. 1B-Aquatic Acute 1-Aquatic Chronic 1;H303-H317-H410

CANTHOXAL

15462-06-06

0.1-<1%

Acute Tox. 5-Skin Sens. 1B-Aquatic Acute 2;H303-H317-H401

]alpha-iso-Methylionone

127-51-5

204-846-3

0.1-<1%

Skin Irrit. 3-Skin Sens. 1B-Aquatic Acute 2-Aquatic Chronic 2;H316-H317-H411

ALLYL IONONE

79-78-7

0.1-<1%

Skin Sens. 1B-Aquatic Acute 2-Aquatic Chronic 2;H317-H411

DAVANA OIL

8016-03-03

0.1-<1%

Flam. Liq. 4-Skin Irrit. 3-Skin Sens. 1- Aquatic Acute 2;H227-H316-H317-H401

MOUSSE METRA ( C )

4707-47-5

0.1-<1%

Skin Sens. 1B-Aquatic Acute 2;H317- H401

SANDELA

3407-42-9

0.1-<1%

Skin Irrit. 3-Eye Irrit. 2A-Aquatic Acute 1-Aquatic Chronic 2;H316-H319-H400-

H411

Benzyl cinnamate

103-41-3

203-109-3

0.1-<1%

Acute Tox. 5-Skin Sens. 1B-Aquatic Acute 1-Aquatic Chronic 2;H303-H317-

H400-H411

HELIOTROPIN ( C )

120-57-0

0.1-<1%

Acute Tox. 5-Skin Sens. 1B-Aquatic Acute 2;H303-H317-H401

KEPHALIS

36306-87-3

0.1-<1%

Skin Irrit. 2-Aquatic Acute 2-Aquatic Chronic 2;H315-H411

ALLYL CYCLO HEXYL PROPIONATE

2705-87-5

0.1-<1%

Acute Tox. 4-Acute Tox. 4-Acute Tox. 4-Skin Sens. 1-Aquatic Acute 1-Aquatic

Chronic 1;H302-H312-H317-H332-H410

BASIL OIL VIETNAM

8015-73-4

0.1-<1%

Flam. Liq. 4-Acute Tox. 4-Skin Irrit. 2- Skin Sens. 1-Muta. 2-Carc. 2-Aquatic Acute 2-Aquatic Chronic 3;H227-H302-H315-H317-H341-H351-H401-H412

Eugenol

97-53-0

202-589-1

0.1-<1%

Acute Tox. 5-Skin Irrit. 3-Eye Irrit. 2A-Skin Sens. 1B-Aquatic Acute 2;H303-

H316-H317-H319-H401

DAMASCENONE

23696-85-7

<0.1%

Acute Tox. 5-Skin Irrit. 2-Skin Sens. 1A-Aquatic Acute 2-Aquatic Chronic 2;H313-

H315-H317-H411

Substances with Community workplace exposure limits, not listed above:

Not Applicable

Section 4. First-aid measures

4.1 Description of first aid measures

IF ON SKIN: Wash with plenty of soap and water.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

4.2 Most important symptoms and effects, both acute and delayed

Causes skin irritation.

May cause an allergic skin reaction. Causes serious eye irritation.

4.3 Indication of any immediate medical attention and special treatment needed

None expected, see Section 4.1 for further information.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable media: Carbon dioxide, Dry chemical, Foam.

5.2 Special hazards arising from the substance or mixture

In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds.

5.3 Advice for fire fighters:

In case of insufficient ventilation, wear suitable respiratory equipment.

Section 6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:

Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8.

6.2 Environmental precautions:

Keep away from drains, surface and ground water, and soil.

6.3 Methods and material for containment and cleaning up:

Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations.

6.4 Reference to other sections:

Also refer to sections 8 and 13.

Section 7. Handling and storage

7.1 Precautions for safe handling:

Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product.

7.2 Conditions for safe storage, including any incompatibilities:

Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge.

7.3 Specific end use(s):

Fragrances: Use in accordance with good manufacturing and industrial hygiene practices.

Section 8. Exposure controls/personal protection

8.1 Control parameters

Workplace exposure limits: Not Applicable

8.2 Exposure Controls

Eye / Skin Protection

Wear protective gloves/eye protection/face protection

Respiratory Protection

Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material.

Section 9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance: Clear free-flowing liquid without sediment

Odour: Conforms To Standard

pH:Not determined

Initial boiling point / range: Not determined

Flash point:> 93 °C

Vapour pressure: Not determined

Relative density: 0.9780 - 0.9880

Solubility(ies):Not determined

9.2 Other information:None available

Section 10. Stability and reactivity

10.1 Reactivity:

Presents no significant reactivity hazard, by itself or in contact with water.

10.2 Chemical stability:

Good stability under normal storage conditions.

10.3 Possibility of hazardous reactions:

Not expected under normal conditions of use.

10.4 Conditions to avoid:

Avoid extreme heat.

10.5 Incompatible materials:

Avoid contact with strong acids, alkalis or oxidising agents.

10.6 Hazardous decomposition products:

Not expected.

Section 11. Toxicological information 11.1 Information on toxicological effects

This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in UN GHS.

Causes skin irritation.

May cause an allergic skin reaction.

Causes serious eye irritation.

Assumed Toxicity Value (LD50 or ATE) for Acute Oral Toxicity: >5000

Assumed Toxicity Value (LD50 or ATE) for Acute Dermal Toxicity:>5000

Assumed Toxicity Value (LC50 or ATE) for Acute Inhalation Toxicity: Not Available

Inhalation Route: Not Available

Information about hazardous ingredients in the mixture


Ingredient

CAS

EC

LD50/ATE Oral

LD50/ATE Dermal

LC50/ATE Inhalation

LC50 Route

Benzyl benzoate

120-51-4

204-402-9

1500

4000

Not available

Not available

Coumarin

91-64-5

202-086-7

500

Not available

Not available

Not available

ETHYL MALTOL ( C )

4940-11-8

1200

Not available

Not available

Not available

Refer to Sections 2 and 3 for additional information.

Section 12. Ecological information

12.1 Toxicity:

Very toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability:Not available

12.3 Bioaccumulative potential:Not available

12.4 Mobility in soil:Not available

12.5 Results of PBT and vPvB assessment:

This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.

12.6 Other adverse effects: Not available

Section 13. Disposal considerations

13.1 Waste treatment methods:

Not available Not available Not available

Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal.

Section 14. Transport information

14.1 UN number:UN3082

14.2 UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ISO E SUPER, AMBRETTOLIDE)

14.3 Transport hazard class(es): 9

Sub Risk:

14.4. Packing Group: III

14.5 Environmental hazards:This is an environmentally hazardous substance.

14.6 Special precautions for user: None additional  

14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable

Section 15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Additional formulation properties: 1 entries

15.2 Chemical Safety Assessment

A Chemical Safety Assessment has not been carried out for this product.

Section 16. Other information

Concentration % Limits: EH A1=73.28% EH A2=6.67% EH A3=0.66344234% EH C1=59.71% EH C2=5.67% EH C3=0.56628669% EH C4=36.15% SCI 2=34.60% SCI 3=3. 14% EDI 2A=50.63% SS 1=4.76%

Total Fractional Values:EH A1=1.36 EH A2=14.99 EH A3=150.73 EH C1=1.67 EH C2=17.64 EH C3=176.59 EH C4=2.77 SCI 2=2.89 SCI 3=31.83 EDI 2A=1.98 SS 1=21. 00

Key to revisions:

Not applicable

Key to abbreviations:


Abbreviation

Meaning

Acute Tox. 4

Acute Toxicity Oral Category 4

Acute Tox. 4

Acute Toxicity Dermal Category 4

Acute Tox. 4

Acute Toxicity Inhalation Category 4

Acute Tox. 5

Acute Toxicity Dermal Category 5

Acute Tox. 5

Acute Toxicity Oral Category 5

Aquatic Acute 1

Hazardous to the Aquatic Environment Acute Hazard Category 1

Aquatic Acute 2

Hazardous to the Aquatic Environment Acute Hazard Category 2

Aquatic Acute 3

Hazardous to the Aquatic Environment Acute Hazard Category 3

Aquatic Chronic 1

Hazardous to the Aquatic Environment Long-term Hazard Category 1

Aquatic Chronic 2

Hazardous to the Aquatic Environment Long-term Hazard Category 2

Aquatic Chronic 3

Hazardous to the Aquatic Environment Long-term Hazard Category 3

Asp. Tox 1

Aspiration Hazard Category 1

Carc. 2

Carcinogenicity Category 2

Eye Irrit. 2A

/ Eye Damage / Irritation Category 2A

Eye Irrit. 2B

Eye Damage / Irritation Category 2B

Flam. Liq. 3

Flammable Liquid, Hazard Category 3

Flam. Liq. 4

Flammable Liquid, Hazard Category 4

H226

Flammable liquid and vapour.

H227

Combustible liquid.

H302

Harmful if swallowed.

H303

May be harmful if swallowed.

H304

May be fatal if swallowed and enters airways.

H312

Harmful in contact with skin.

H313

May be harmful in contact with skin.

H315

Causes skin irritation.

H316

Causes mild skin irritation.

H317

May cause an allergic skin reaction.

H319

Causes serious eye irritation.

H320

Causes eye irritation.

H332

Harmful if inhaled.

IH341

Suspected of causing genetic defects (exposure route).

H351

Suspected of causing cancer (exposure route).

H361

Suspected of damaging fertility or the unborn child (exposure route).

H400

Very toxic to aquatic life.

H401

Toxic to aquatic life.

H402

Harmful to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

H411

Toxic to aquatic life with long lasting effects.

H412

Harmful to aquatic life with long lasting effects.

Muta. 2

Germ Cell Mutagenicity Category 2

P202

Do not handle until all safety precautions have been read and understood.

P210

Keep away from heat, sparks, open flames and hot surfaces. No smoking.

P233

Keep container tightly closed.

P240

Ground/bond container and receiving equipment.

P241

Use explosion-proof electrical, ventilating and lighting equipment.

P242

Use only non-sparking tools.

P243

Take precautionary measures against static discharge.

P261

Avoid breathing vapour or dust.

P264

Wash hands and other contacted skin thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P271

Use only outdoors or in a well-ventilated area.

P272

Contaminated work clothing should not be allowed out of the workplace.

P273

Avoid release to the environment.

P280

Wear protective gloves/eye protection/face protection.

P301/310

IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P301/312

IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell.

P302/352

IF ON SKIN: Wash with plenty of soap and water.

P303/361/353

IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.

P304/340

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

The information in this safety data sheet is to the best of our knowledge true and accurate but all data, instructions, recommendations and/or suggestions are made without guarantee.

CERTIFICATE OF CONFORMITY WITH IFRA STANDARDS

This Certificate assesses the conformity of the fragrance mixture with IFRA Standards and provides restrictions for use as necessary. It is based only on those materials subject to IFRA Standards for the toxicity endpoints described in each Standard.

This Certificate does therefore not replace a comprehensive safety assessment of the fragrance mixture.

SCOPE OF THE CERTIFICATE:

Calle 23

COMPULSORY INFORMATION:

We certify that the above mixture is in compliance with the Standards of the INTERNATIONAL FRAGRANCE ASSOCIATION (IFRA), up to and including the 49th Amendment to the IFRA Code of Practice (published January 2020), provided it is used in the following categories at a maximum concentration level of:


IFRA Categories

[see Annex 1 below for details]

Maximum Level of use (%)

IFRA Category 1

Not approved

IFRA Category 2

1.55%

IFRA Category 3

0.63%

IFRA Category 4

30.00%

IFRA Category 5A

7.25%

IFRA Category 5B

0.83%

IFRA Category 5C

1.26%

IFRA Category 5D

0.28%

IFRA Category 6

Not approved

IFRA Category 7A

1.03%

IFRA Category 7B

1.03%

IFRA Category 8

0.28%

IFRA Category 9

4.33%

IFRA Category 10A

4.33%

IFRA Category 10B

9.33%

IFRA Category 11A

0.28%

IFRA Category 11B

0.28%

IFRA Category 12

Not limited